When the superstitious Darlings come to town with their mountain incantations for Charlene's divorce ("Divorce, Mountain Style", Episode #121), it's up to Barney to nullify Charlene's renewed romantic designs on Andy by invoking the Curse of the White Horse.
Never mind that Barney is allergic to horse hair (if you must know): He still must accomplish his mission of dressing in black and riding a white horse east to west in the full moon.